| # | Date | Result | Against | Stadium |
|---|---|---|---|---|
| 1 | 07.11.1964 | 1 - 1 | Fulham | Craven Cottage |
| 2 | 21.11.1964 | 1 - 1 | Stoke City | Victoria Ground |
| 3 | 28.11.1964 | 1 - 1 | Tottenham | Anfield |
| 4 | 05.12.1964 | 5 - 1 | Burnley | Turf Moor |
| 5 | 12.12.1964 | 0 - 0 | Arsenal | Highbury |
| 6 | 13.03.1965 | 0 - 3 | Sheffield United | Bramall Lane |
| 7 | 20.03.1965 | 3 - 2 | Fulham | Anfield |
| 8 | 06.04.1965 | 0 - 3 | WBA | Anfield |
| 9 | 09.04.1965 | 0 - 3 | Tottenham | White Hart Lane |
| 10 | 17.04.1965 | 1 - 1 | Burnley | Anfield |
| 11 | 19.04.1965 | 2 - 0 | Chelsea | Anfield |
| 12 | 24.04.1965 | 0 - 3 | Manchester United | Old Trafford |
| 13 | 26.04.1965 | 3 - 1 | Wolves | Molineux |
| 14 | 01.05.1965 | 2 - 1 | Leeds United | Wembley |
| 15 | 04.05.1965 | 3 - 1 | Inter Milan | Anfield |
| 16 | 12.05.1965 | 0 - 3 | Inter Milan | San Siro |
| 17 | 14.08.1965 | 2 - 2 | Manchester United | Old Trafford |
| 18 | 21.08.1965 | 3 - 1 | Leicester City | Filbert Street |
| 19 | 25.08.1965 | 0 - 1 | Sheffield United | Anfield |
| 20 | 04.09.1965 | 3 - 2 | Blackpool | Bloomfield Road |
| 21 | 15.09.1965 | 1 - 1 | West Ham United | Anfield |
| 22 | 18.09.1965 | 1 - 2 | Tottenham | White Hart Lane |
| 23 | 25.09.1965 | 5 - 0 | Everton | Anfield |
| 24 | 29.09.1965 | 0 - 1 | Juventus | Stadio Communale |
| 25 | 02.10.1965 | 3 - 1 | Aston Villa | Anfield |
| 26 | 09.10.1965 | 0 - 2 | Manchester United | Old Trafford |
| 27 | 13.10.1965 | 2 - 0 | Juventus | Anfield |
| 28 | 16.10.1965 | 2 - 0 | Newcastle United | Anfield |
| 29 | 23.10.1965 | 0 - 3 | WBA | The Hawthorns |
| 30 | 30.10.1965 | 4 - 0 | Nottingham Forest | Anfield |
| 31 | 06.11.1965 | 2 - 0 | Sheffield Wednesday | Hillsborough |
| 32 | 13.11.1965 | 5 - 0 | Northampton Town | Anfield |
| 33 | 17.11.1965 | 5 - 2 | Blackburn Rovers | Anfield |
| 34 | 04.12.1965 | 1 - 0 | Chelsea | Stamford Bridge |
| 35 | 11.12.1965 | 4 - 2 | Arsenal | Anfield |
| 36 | 15.12.1965 | 2 - 1 | Standard Liege | Stade de Sclessin |
| 37 | 18.12.1965 | 0 - 0 | Newcastle United | St James' Park |
| 38 | 26.03.1966 | 3 - 0 | Aston Villa | Villa Park |
| 39 | 06.04.1966 | 1 - 0 | Sheffield Wednesday | Anfield |
| 40 | 09.04.1966 | 0 - 0 | Northampton Town | County Ground |
| 41 | 11.04.1966 | 2 - 2 | Sunderland | Roker Park |
| 42 | 16.04.1966 | 2 - 0 | Stoke City | Anfield |
| 43 | 19.04.1966 | 2 - 0 | Celtic | Anfield |
| 44 | 13.08.1966 | 1 - 0 | Everton | Goodison Park |
| 45 | 20.08.1966 | 3 - 2 | Leicester City | Anfield |
| 46 | 24.08.1966 | 1 - 2 | Manchester City | Maine Road |
| 47 | 27.08.1966 | 1 - 3 | Everton | Goodison Park |
| 48 | 30.08.1966 | 3 - 2 | Manchester City | Anfield |
| 49 | 03.09.1966 | 1 - 1 | West Ham United | Upton Park |
| 50 | 05.09.1966 | 2 - 1 | Blackpool | Bloomfield Road |
| 51 | 10.09.1966 | 1 - 1 | Sheffield Wednesday | Anfield |
| 52 | 17.09.1966 | 2 - 1 | Southampton | The Dell |
| 53 | 24.09.1966 | 2 - 2 | Sunderland | Anfield |
| 54 | 28.09.1966 | 2 - 0 | Petrolul Ploiesti | Anfield |
| 55 | 01.10.1966 | 3 - 2 | Aston Villa | Villa Park |
| 56 | 08.10.1966 | 2 - 2 | Fulham | Anfield |
| 57 | 12.10.1966 | 1 - 3 | Petrolul Ploiesti | Ploiesti Stadium |
| 58 | 15.10.1966 | 1 - 1 | Nottingham Forest | City Ground |
| 59 | 19.10.1966 | 2 - 0 | Petrolul Ploiesti | Heysel |
| 60 | 29.10.1966 | 0 - 2 | Stoke City | Victoria Ground |
| 61 | 05.11.1966 | 4 - 0 | Nottingham Forest | Anfield |
| 62 | 09.11.1966 | 2 - 0 | Burnley | Anfield |
| 63 | 12.11.1966 | 2 - 0 | Newcastle United | St James' Park |
| 64 | 19.11.1966 | 5 - 0 | Leeds United | Anfield |
| 65 | 26.11.1966 | 1 - 2 | WBA | The Hawthorns |
| 66 | 03.12.1966 | 1 - 0 | Sheffield United | Anfield |
| 67 | 07.12.1966 | 1 - 5 | Ajax | Olympic Stadium |
| 68 | 10.12.1966 | 2 - 2 | Manchester United | Old Trafford |
| 69 | 14.12.1966 | 2 - 2 | Ajax | Anfield |
| 70 | 24.12.1966 | 2 - 1 | Chelsea | Stamford Bridge |
| 71 | 26.12.1966 | 2 - 1 | Chelsea | Anfield |
| 72 | 31.12.1966 | 0 - 0 | Everton | Anfield |
| 73 | 07.01.1967 | 2 - 0 | West Ham United | Anfield |
| 74 | 14.01.1967 | 1 - 0 | Sheffield Wednesday | Hillsborough |
| 75 | 18.01.1967 | 1 - 2 | Leicester City | Filbert Street |
| 76 | 21.01.1967 | 2 - 1 | Southampton | Anfield |
| 77 | 28.01.1967 | 0 - 0 | Watford | Vicarage Road |
| 78 | 01.02.1967 | 3 - 1 | Watford | Anfield |
| 79 | 04.02.1967 | 2 - 2 | Sunderland | Roker Park |
| 80 | 11.02.1967 | 1 - 0 | Aston Villa | Anfield |
| 81 | 18.02.1967 | 1 - 0 | Aston Villa | Anfield |
| 82 | 25.02.1967 | 2 - 2 | Fulham | Craven Cottage |
| 83 | 18.03.1967 | 0 - 1 | Burnley | Turf Moor |
| 84 | 25.03.1967 | 0 - 0 | Manchester United | Anfield |
| 85 | 28.04.1967 | 1 - 0 | Sheffield United | Bramall Lane |
| 86 | 03.05.1967 | 1 - 2 | Leeds United | Elland Road |
| 87 | 06.05.1967 | 0 - 0 | Tottenham | Anfield |
| 88 | 13.05.1967 | 1 - 3 | Blackpool | Anfield |
| 89 | 24.10.1967 | 1 - 1 | Burnley | Turf Moor |
| 90 | 09.12.1967 | 2 - 0 | Leeds United | Anfield |
| 91 | 16.12.1967 | 1 - 1 | Manchester City | Anfield |
| 92 | 26.12.1967 | 1 - 1 | Coventry City | Highfield Road |
| 93 | 30.12.1967 | 1 - 0 | Coventry City | Anfield |
| 94 | 06.01.1968 | 4 - 1 | WBA | Anfield |
| 95 | 09.01.1968 | 0 - 1 | Ferencvaros | Anfield |
| 96 | 20.01.1968 | 2 - 0 | Southampton | Anfield |
| 97 | 27.01.1968 | 0 - 0 | Bournemouth & Boscombe Athletic | Dean Court |
| 98 | 30.01.1968 | 4 - 1 | Bournemouth & Boscombe Athletic | Anfield |
| 99 | 03.02.1968 | 0 - 1 | Everton | Goodison Park |
| 100 | 12.02.1968 | 1 - 3 | Chelsea | Stamford Bridge |
| 101 | 17.02.1968 | 0 - 0 | Walsall | Fellows Park |
| 102 | 19.02.1968 | 5 - 2 | Walsall | Anfield |
| 103 | 24.02.1968 | 3 - 1 | Leicester City | Anfield |
| 104 | 09.03.1968 | 1 - 1 | Tottenham | White Hart Lane |
| 105 | 12.03.1968 | 2 - 1 | Tottenham | Anfield |
| 106 | 16.03.1968 | 3 - 2 | Burnley | Anfield |
| 107 | 23.03.1968 | 2 - 1 | Sheffield Wednesday | Hillsborough |
| 108 | 30.03.1968 | 0 - 0 | WBA | The Hawthorns |
| 109 | 06.04.1968 | 2 - 1 | Manchester United | Old Trafford |
| 110 | 08.04.1968 | 1 - 1 | WBA | Anfield |
| 111 | 12.04.1968 | 1 - 2 | Sheffield United | Anfield |
| 112 | 13.04.1968 | 2 - 1 | Sunderland | Anfield |
| 113 | 15.04.1968 | 1 - 1 | Sheffield United | Bramall Lane |
| 114 | 18.04.1968 | 1 - 2 | WBA | Maine Road |
| 115 | 04.05.1968 | 2 - 1 | Leeds United | Elland Road |
| 116 | 11.05.1968 | 6 - 1 | Nottingham Forest | Anfield |
| 117 | 15.05.1968 | 1 - 2 | Stoke City | Victoria Ground |
| 118 | 17.08.1968 | 1 - 1 | Arsenal | Highbury |
| 119 | 31.08.1968 | 0 - 1 | Leeds United | Elland Road |
| 120 | 18.09.1968 | 1 - 2 | Athletic Bilbao | San Mames |
| 121 | 25.09.1968 | 2 - 0 | Swansea Town | Anfield |
| 122 | 05.10.1968 | 4 - 0 | Burnley | Turf Moor |
| 123 | 12.10.1968 | 2 - 0 | Manchester United | Anfield |
| 124 | 15.10.1968 | 1 - 2 | Arsenal | Highbury |
| 125 | 19.10.1968 | 1 - 2 | Tottenham | White Hart Lane |
| 126 | 26.10.1968 | 2 - 1 | Newcastle United | Anfield |
| 127 | 02.11.1968 | 0 - 0 | WBA | The Hawthorns |
| 128 | 09.11.1968 | 2 - 1 | Chelsea | Anfield |
| 129 | 16.11.1968 | 2 - 1 | Sheffield Wednesday | Hillsborough |
| 130 | 23.11.1968 | 2 - 0 | Coventry City | Anfield |
| 131 | 30.11.1968 | 1 - 0 | Nottingham Forest | City Ground |
| 132 | 03.12.1968 | 1 - 0 | Southampton | Anfield |
| 133 | 07.12.1968 | 2 - 0 | West Ham United | Anfield |
| 134 | 14.12.1968 | 0 - 1 | Manchester United | Old Trafford |
| 135 | 21.12.1968 | 1 - 0 | Tottenham | Anfield |
| 136 | 26.12.1968 | 1 - 1 | Burnley | Anfield |
| 137 | 04.01.1969 | 2 - 0 | Doncaster Rovers | Anfield |
| 138 | 11.01.1969 | 1 - 0 | WBA | Anfield |
| 139 | 18.01.1969 | 2 - 1 | Chelsea | Stamford Bridge |
| 140 | 25.01.1969 | 2 - 1 | Burnley | Anfield |
| 141 | 01.02.1969 | 1 - 0 | Sheffield Wednesday | Anfield |
| 142 | 15.02.1969 | 0 - 2 | Nottingham Forest | Anfield |
| 143 | 22.02.1969 | 1 - 1 | West Ham United | Upton Park |
| 144 | 01.03.1969 | 0 - 0 | Leicester City | Filbert Street |
| 145 | 03.03.1969 | 0 - 1 | Leicester City | Anfield |
| 146 | 15.03.1969 | 2 - 0 | Sunderland | Roker Park |
| 147 | 31.03.1969 | 1 - 1 | Arsenal | Anfield |
| 148 | 05.04.1969 | 1 - 0 | Wolves | Anfield |
| 149 | 07.04.1969 | 0 - 0 | Stoke City | Victoria Ground |
| 150 | 12.04.1969 | 2 - 1 | Leicester City | Filbert Street |
| 151 | 19.04.1969 | 4 - 0 | Ipswich Town | Anfield |
| 152 | 22.04.1969 | 0 - 0 | Coventry City | Highfield Road |
| 153 | 28.04.1969 | 0 - 0 | Leeds United | Anfield |
| 154 | 12.05.1969 | 0 - 1 | Manchester City | Maine Road |
| 155 | 17.05.1969 | 1 - 1 | Newcastle United | St James' Park |
| 156 | 09.08.1969 | 4 - 1 | Chelsea | Anfield |
| 157 | 12.08.1969 | 3 - 2 | Manchester City | Anfield |
| 158 | 16.08.1969 | 2 - 0 | Tottenham | White Hart Lane |
| 159 | 20.08.1969 | 2 - 0 | Manchester City | Maine Road |
| 160 | 23.08.1969 | 3 - 3 | Burnley | Anfield |
| 161 | 27.08.1969 | 3 - 1 | Crystal Palace | Selhurst Park |
| 162 | 30.08.1969 | 1 - 1 | Sheffield Wednesday | Hillsborough |
| 163 | 03.09.1969 | 2 - 1 | Watford | Vicarage Road |
| 164 | 06.09.1969 | 2 - 1 | Coventry City | Anfield |
| 165 | 09.09.1969 | 2 - 0 | Sunderland | Anfield |
| 166 | 13.09.1969 | 0 - 1 | Manchester United | Old Trafford |
| 167 | 16.09.1969 | 10 - 0 | Dundalk | Anfield |
| 168 | 20.09.1969 | 3 - 1 | Stoke City | Anfield |
| 169 | 24.09.1969 | 2 - 3 | Manchester City | Maine Road |
| 170 | 27.09.1969 | 2 - 2 | WBA | The Hawthorns |
| 171 | 30.09.1969 | 4 - 0 | Dundalk | Oriel Park |
| 172 | 04.10.1969 | 1 - 1 | Nottingham Forest | Anfield |
| 173 | 07.10.1969 | 0 - 0 | Tottenham | Anfield |
| 174 | 11.10.1969 | 0 - 1 | Newcastle United | St James' Park |
| 175 | 18.10.1969 | 2 - 2 | Ipswich Town | Portman Road |
| 176 | 25.10.1969 | 4 - 1 | Southampton | Anfield |
| 177 | 01.11.1969 | 0 - 4 | Derby | Baseball Ground |
| 178 | 08.11.1969 | 0 - 0 | Wolves | Anfield |
| 179 | 12.11.1969 | 0 - 1 | Vitoria Setubal | Estadio Bonfim |
| 180 | 15.11.1969 | 2 - 0 | West Ham United | Anfield |
| 181 | 22.11.1969 | 1 - 1 | Leeds United | Elland Road |
| 182 | 26.11.1969 | 3 - 2 | Vitoria Setubal | Anfield |
| 183 | 29.11.1969 | 0 - 1 | Arsenal | Anfield |
| 184 | 06.12.1969 | 3 - 0 | Everton | Goodison Park |
| 185 | 13.12.1969 | 1 - 4 | Manchester United | Anfield |
| 186 | 26.12.1969 | 5 - 1 | Burnley | Turf Moor |
| 187 | 07.01.1970 | 1 - 1 | Coventry City | Highfield Road |
| 188 | 10.01.1970 | 2 - 0 | Stoke City | Victoria Ground |
| 189 | 12.01.1970 | 3 - 0 | Coventry City | Anfield |
| 190 | 17.01.1970 | 1 - 1 | WBA | Anfield |
| 191 | 24.01.1970 | 3 - 1 | Wrexham | Anfield |
| 192 | 31.01.1970 | 0 - 1 | Nottingham Forest | City Ground |
| 193 | 07.02.1970 | 0 - 0 | Leicester City | Anfield |
| 194 | 11.02.1970 | 2 - 0 | Leicester City | Filbert Street |
| 195 | 16.02.1970 | 0 - 0 | Newcastle United | Anfield |
| 196 | 21.02.1970 | 0 - 1 | Watford | Vicarage Road |
| 197 | 28.02.1970 | 0 - 2 | Derby | Anfield |
| 198 | 03.03.1970 | 3 - 2 | Coventry City | Highfield Road |
| 199 | 07.03.1970 | 0 - 0 | Leeds United | Anfield |
| 200 | 11.03.1970 | 1 - 0 | Southampton | The Dell |
| 201 | 21.03.1970 | 0 - 2 | Everton | Anfield |