| Date | Result | Against | Stadium | Competition |
|---|---|---|---|---|
| 15.10.1968 | 1 - 2 | Arsenal | Highbury | League Cup 4th round |
| 27.10.1971 | 1 - 2 | West Ham United | Upton Park | League Cup 4th round |
| 31.10.1972 | 2 - 2 | Leeds United | Anfield | League Cup 4th round |
| 27.11.1973 | 0 - 0 | Hull City | Boothferry Park | League Cup 4th round |
| 12.11.1974 | 0 - 1 | Middlesbrough | Anfield | League Cup 4th round |
| 29.11.1977 | 2 - 2 | Coventry City | Anfield | League Cup 4th round |
| 30.10.1979 | 2 - 0 | Exeter City | Anfield | League Cup 4th round |
| 28.10.1980 | 4 - 1 | Portsmouth | Anfield | League Cup 4th round |
| 01.12.1981 | 0 - 0 | Arsenal | Highbury | League Cup 4th round |
| 30.11.1982 | 2 - 0 | Norwich City | Anfield | League Cup 4th round |
| 20.12.1983 | 1 - 1 | Birmingham City | St Andrews | League Cup 4th round |
| 26.11.1985 | 2 - 1 | Manchester United | Anfield | League Cup 4th round |
| 19.11.1986 | 0 - 0 | Coventry City | Highfield Road | League Cup 4th round |
| 30.11.1988 | 1 - 4 | West Ham United | Upton Park | League Cup 4th round |
| 03.12.1991 | 0 - 1 | Peterborough United | London Road | League Cup 4th round |
| 01.12.1992 | 1 - 1 | Crystal Palace | Anfield | League Cup 4th round |
| 01.12.1993 | 1 - 1 | Wimbledon | Anfield | League Cup 4th round |
| 30.11.1994 | 3 - 1 | Blackburn Rovers | Ewood Park | League Cup 4th round |
| 29.11.1995 | 0 - 1 | Newcastle United | Anfield | League Cup 4th round |
| 27.11.1996 | 4 - 2 | Arsenal | Anfield | League Cup 4th round |
| 18.11.1997 | 3 - 0 | Grimsby Town | Anfield | League Cup 4th round |
| 10.11.1998 | 1 - 3 | Tottenham Hotspur | Anfield | League Cup 4th round |
| 29.11.2000 | 8 - 0 | Stoke City | Britannia Stadium | League Cup 4th round |
| 04.12.2002 | 1 - 1 | Ipswich Town | Anfield | League Cup 4th round |
| 03.12.2003 | 2 - 3 | Bolton Wanderers | Anfield | League Cup 4th round |
| 10.11.2004 | 2 - 0 | Middlesbrough | Anfield | League Cup 4th round |
| 08.11.2006 | 1 - 0 | Birmingham City | St Andrews | League Cup 4th round |
| 31.10.2007 | 2 - 1 | Cardiff City | Anfield | League Cup 4th round |
| 12.11.2008 | 2 - 4 | Tottenham Hotspur | White Hart Lane | League Cup 4th round |
| 28.10.2009 | 1 - 2 | Arsenal | Emirates Stadium | League Cup 4th round |
| 26.10.2011 | 2 - 1 | Stoke City | Britannia Stadium | League Cup 4th round |
| 31.10.2012 | 1 - 3 | Swansea City | Anfield | League Cup 4th round |
| 28.10.2014 | 2 - 1 | Swansea City | Anfield | League Cup 4th round |
| 28.10.2015 | 1 - 0 | Bournemouth | Anfield | League Cup 4th round |
| 25.10.2016 | 2 - 1 | Tottenham Hotspur | Anfield | League Cup 4th round |
| 30.10.2019 | 5 - 5 | Arsenal | Anfield | League Cup 4th round |
| 01.10.2020 | 0 - 0 | Arsenal | Anfield | League Cup 4th round |
| 27.10.2021 | 2 - 0 | Preston North End | Deepdale | League Cup 4th round |
| 22.12.2022 | 2 - 3 | Manchester City | Etihad Stadium | League Cup 4th round |
| 01.11.2023 | 2 - 1 | Bournemouth | Dean Court | League Cup 4th round |
| 30.10.2024 | 3 - 2 | Brighton & Hove Albion | American Express Community Stadium | League Cup 4th round |
| 29.10.2025 | 0 - 3 | Crystal Palace | Anfield | League Cup 4th round |