| # | Date | Result | Against | Competition | Started/Sub | Minute | Goalscorer |
|---|---|---|---|---|---|---|---|
| 1 | 19 Aug | 4 - 0 | Stoke City | Premier League | Started | 4 | Fernando Torres |
| 2 | 19 Aug | 4 - 0 | Stoke City | Premier League | Started | 78 | Dirk Kuyt |
| 3 | 12 Sep | 4 - 0 | Burnley | Premier League | Started | 61 | Yossi Benayoun |
| 4 | 19 Sep | 3 - 2 | West Ham United | Premier League | Started | 42 | Dirk Kuyt |
| 5 | 21 Nov | 2 - 2 | Manchester City | Premier League | Started | 50 | Martin Skrtel |
| 6 | 09 Dec | 1 - 2 | Fiorentina | Champions L. 1st Group Ph. | Started | 43 | Yossi Benayoun |
| 7 | 06 Feb | 1 - 0 | Everton | Premier League | Started | 55 | Dirk Kuyt |
| 8 | 01 Apr | 1 - 2 | Benfica | Europa League QF | Started | 9 | Daniel Agger |
| 9 | 08 Apr | 4 - 1 | Benfica | Europa League QF | Started | 27 | Dirk Kuyt |
| 10 | 08 Apr | 4 - 1 | Benfica | Europa League QF | Started | 34 | Lucas Leiva |
| 11 | 19 Apr | 3 - 0 | West Ham United | Premier League | Started | 19 | Yossi Benayoun |