| # | Date | Result | Against | Competition | Started/Sub | Minute | Goalscorer |
|---|---|---|---|---|---|---|---|
| 1 | 01 Oct | 3 - 1 | PSV Eindhoven | Champions L. 1st Group Ph. | Started | 76 | Steven Gerrard |
| 2 | 08 Nov | 3 - 0 | WBA | Premier League | Started | 43 | Robbie Keane |
| 3 | 15 Nov | 2 - 0 | Bolton Wanderers | Premier League | Started | 28 | Dirk Kuyt |
| 4 | 01 Feb | 2 - 0 | Chelsea | Premier League | Started | 89 | Fernando Torres |
| 5 | 25 Feb | 1 - 0 | Real Madrid | CL 1st knockout r. 1st leg | Started | 82 | Yossi Benayoun |
| 6 | 03 May | 3 - 0 | Newcastle United | Premier League | Started | 87 | Lucas Leiva |