Tivoli Stadion | Thursday 29 July 2021 at 19:20 UK local time
| Hertha Berlin | 4 | - | 3 | Liverpool |
| Caoimhin Kelleher |
| Trent Alexander-Arnold |
| Kostas Tsimikas |
| Naby Keita |
| Ibrahima Konaté |
| Joël Matip |
| James Milner |
| Harvey Elliott |
| Sadio Mané |
| Takumi Minamino |
| Mohamed Salah |
| Adrián San Miguel 46′ |
| Kostas Tsimikas replaced by Andy Robertson 46′ |
| Ibrahima Konaté replaced by Rhys Williams 46′ |
| Joël Matip replaced by Nathaniel Phillips 46′ |
| Harvey Elliott replaced by Curtis Jones 46′ |
| Takumi Minamino replaced by Alex Oxlade-Chamberlain 46′ |
| Trent Alexander-Arnold replaced by Neco Williams 63′ |
| Naby Keita replaced by Leighton Clarkson 63′ |
| James Milner replaced by Tyler Morton 63′ |
| Sadio Mané replaced by Kaide Gordon 63′ |
| Mohamed Salah replaced by Diogo Jota 63′ |
| Rhys Williams replaced by Joe Gomez 69′ |
| Nathaniel Phillips replaced by Virgil Van Dijk 69′ |
| Harvey Davies |
| Conor Bradley |
| Billy Koumetio |
| Owen Beck |
| Jake Cain |
Opposition
Lineup: Schwolow, Pekarik (Zeefuik 68), Plattenhardt (Mittelstaedt 68),Ascacibar (Darida 25), Stark (Kluenter 68), Dardai (Gechter 68), Selke (Werthmueller 68), Serdar (Dirkner 45), Dilrosun (Jastrzembski 68), Boateng (Jovetic 60), Lukebakio (Morgenstern 68)
Goals: Ascacibar 21, Serdar 31, Jovetic 66, 80
